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Quantum Mechanics · Wave-Particle Duality

de Broglie Matter Waves

λ = h / p = h / (mv)  ·  p = ℏk  ·  E = hf
⚛️Electron
🔵Proton
Neutron
Ball
slowfast
localizedspread out
Propagating Matter Wave — Real part of ψ(x,t)
Wavelength λ
de Broglie
Momentum p
kg·m/s
Phase Velocity
v_phase = E/p
Quantum?
Yes
λ > atom size
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Wavelength Scale — All particles at same speed
Quantum Number n — Standing Matter Waves
n = 1
n = 2
n = 3
n = 4
n = 5
n = 6
de Broglie Standing Wave on Circular Orbit
Quantum # n
1
integer only
Orbit radius
a₀
r = n²·a₀
Wavelengths / orbit
1
2πr = nλ
Angular Momentum
L = nℏ (Bohr)
Bohr's Quantization Explained by de Broglie: An electron can only exist in orbits where its matter wave forms a perfect standing wave — the wave must close on itself: 2πr = nλ. Non-integer n values would cause destructive interference, making those orbits forbidden. This explains why angular momentum is quantized: L = nℏ follows directly from 2πr = nλ combined with λ = h/p.